| 描述高自旋体系的密度算符方法 |
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| 引用本文： | 林东海,吴钦义.描述高自旋体系的密度算符方法[J].波谱学杂志,1993,10(4):413-423. |
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| 作者姓名： | 林东海 吴钦义 |
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| 作者单位： | 中国科学院武汉物理研究所波谱与原子分子物理国家重点实验室, 武汉 430071 |
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| 摘 要： | 提出了一种描述高自旋弱偶合体系NMR实验谱的密度算符方法,给出了高自旋体系密度算符在自旋偶合作用下的演化公式。以氘核(2D)为例,计算了重聚INEPT和同核COSY实验谱。
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| 关 键 词： | 密度算符 高自旋体系 |
| 收稿时间： | 1992-08-13 |
A NEW DENSITY OPERATOR FOR DESCRIBING HIGH-SPIN NUCLEI SYSTEMS |
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| Lin Donghai and Wu Qinyi.A NEW DENSITY OPERATOR FOR DESCRIBING HIGH-SPIN NUCLEI SYSTEMS[J].Chinese Journal of Magnetic Resonance,1993,10(4):413-423. |
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| Authors: | Lin Donghai and Wu Qinyi |
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| Institution: | State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics, The Chinese Academy of Sciences, Wuhan 430071 |
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| Abstract: | A new density operator formalism for discribing weakly coupled high-spin systems was proposed. The formula of evolution of density operators under the effect of spin-spin coupling were derived. Some experiments were analysed including refocused INEPT and homonuclear COSY (for D nuclear). |
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| Keywords: | Density operator High-spin system |
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