Intramolecular [4 + 2] cycloadditions of benzynes with conjugated enynes, arenynes, and dienes |
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| Authors: | Hayes Martin E Shinokubo Hiroshi Danheiser Rick L |
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| Institution: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. |
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| Abstract: | Benzynes generated by the reaction of o-(trimethylsilyl)aryl triflates with TBAT participate in intramolecular 4 + 2] cycloadditions with conjugated enynes, arenynes, and dienes to furnish highly condensed polycyclic aromatic compounds. reaction: see text] |
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