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Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by Cu(Ⅱ)-imine complex
作者姓名:Ning Ning Wan  Yong Lei Yang  Wen Ping Wang  Zheng Feng Xie  Ji De Wang
作者单位:a College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China;b Key Laboratory of Oil & Gas Fine Chemicals of Ministry of Education, Xinjiang University, Urumqi 830046, China
基金项目:the financial support from the National Natural Science Foundation of China(Nos.20962018, 20862015,20762009 and 20562011)
摘    要:A series of new ligands L1-L7 were readily prepared in one step.Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a novel Cu(Ⅱ)-L complex has been developed.The remarkable advantages of this reaction are mild reaction conditions,simple workup procedure,high yields of products and the use of ethanol as a green solvent.

关 键 词:Friedel-Crafts  alkylation  Indole  Nitroalkene  Copper  Imine
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