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CaSO4·(1/2) H2O粉末中结晶水与吸附水1H的Goldman-Shen实验
引用本文:李geng颖 邬学文. CaSO4·(1/2) H2O粉末中结晶水与吸附水1H的Goldman-Shen实验[J]. 波谱学杂志, 1991, 8(1): 107-112
作者姓名:李geng颖 邬学文
作者单位:华东师范大学分析测试中心 上海 200062
摘    要:本文利用Goldman-Shen脉冲序列测量了CaSO4·(1/2) H2O样品中结晶水与吸附水1H的交叉弛豫时间为55.1ms。在实验中,发现剩余窄线的磁化矢量随时间的衰减有三个过程。本文对此现象作了一些分析讨论。

关 键 词:核磁共振  固体样品  交叉弛豫  
收稿时间:1990-04-24

1H GOLDMAN-SHEN EXPERIMENT ON CRYSTALLINE AND ADSORBED WATERS IN CaSO4·(1/2) H2O POWDER
Li Gengying,Wu Xuewen. 1H GOLDMAN-SHEN EXPERIMENT ON CRYSTALLINE AND ADSORBED WATERS IN CaSO4·(1/2) H2O POWDER[J]. Chinese Journal of Magnetic Resonance, 1991, 8(1): 107-112
Authors:Li Gengying  Wu Xuewen
Affiliation:NMR Lab., Analytical Center, East China Normal University, Shanghai 200062
Abstract:1H cross relaxation time between crystalline and adsorbed waters inCaSO4 1/2 H2O powder was found to be 55.1 ms by use of the Goldman-Shen pulse sequence. In experiment, it was discovered that the narrow component ofthe 1H spectrum line decays with three time constants. The present paper gives some explanations for the experimental results.
Keywords:Nuclear magnetic resonance  Solid sample  Cross relaxation  
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