| Synthesis and Crystal Structure of an Incomplete Cubane-type Mo3S4 Cluster with the N-N-O Type Tridentate Ligand：[Mo3S4[NH2CH2CH（O）CH2NH2]3}（DTP）- （H2O）2- （DMF） |
| |
| 作者姓名： | HU Rui-Feng QIN Ye-Yan KANG Yao ZHANG Jian WEN Yi-Hang LI Zhao-Ji CHEN Jiu-Tong YAO Yuan-Gen |
| |
| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
| |
| 基金项目： | This work was supported by the State Key Basic Research and Development Plan of China (001CB108906)the NNSF of China (20173063) NSF of Fujian Province (E0020001) |
| |
| 摘 要： | 1 INTRODUCTION It is of significance to investigate the reactivity of trinuclear molybdenum sulfide cluster compounds for their interesting chemistry and potential applica- tions on catalysis1, 2]. The earlier researches estab- lished that Mo3S4(DTP)4(H2O) has three ligand substitution sites: the loosely-coordinated ligand H2O, the bridging DTP and the terminal DTP ligands. Among these three reaction sites, the reac- tivity follows the sequence of H2O > b-DTP > t-DTP. The loose…
|
| 关 键 词： | 合成 晶体结构 立方烷 氮-氮-氧型三齿配合基 钼硫簇 配体取代反应 |
| 本文献已被 CNKI 等数据库收录！ |
