Evidence for quasi-intramolecular acid-base reactions in solutions of transition metal ammine complexes |
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| Authors: | Kótai László Horváth Tibor Szentmihályi Klára Keszler Ágnes |
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| Affiliation: | (1) Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1525 Budapest, P.O. Box. 17, Hungary |
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| Abstract: | We have investigated the effect of temperature on the postulated quasi-intramolecular acid-base reactions in aqueous solutions of Cu(NH3)4(MnO4)2 and Ag(NH3)2ClO4. Pure ammonium permanganate and perchlorate were obtained above 5  C and at room temperature, respectively, due to quasi-intramolecular acid-base reactions. |
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