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| 一个新颖的二重互穿的三维无机-有机杂化化合物[Cd(C5H3N2O2)2(H2O)]n的合成和晶体结构 | |
| 引用本文： | 张 鹏,王恩波,邢长宇,康平利,李 凯.一个新颖的二重互穿的三维无机-有机杂化化合物[Cd(C5H3N2O2)2(H2O)]n的合成和晶体结构[J].无机化学学报,2009,25(3):560-562. |
| 作者姓名： | 张 鹏 王恩波 邢长宇 康平利 李 凯 |
| 作者单位： | 1. 辽宁大学化学院,沈阳,110036;东北师范大学化学学院,长春,130024 2. 东北师范大学化学学院,长春,130024 3. 辽宁大学化学院,沈阳,110036 |
| 摘 要： | 近年来,由于无机-有机杂化化合物表现出独特的结构多样性以及在催化、光化学、电学和磁学等方面的巨大潜在应用.而引起了科学家们的广泛关注1-4]. |
| 关 键 词： | 二重互穿 三维 水热合成 晶体结构 |
Synthesis and Crystal Structure of a Two-Fold Three-Dimesional Inorganic-Organic Hybrid Complex [Cd(C5H3N2O2)2(H2O)]n |
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| ZHANG Peng,WANG En-Bo,XING Chang-Yu,KANG Ping-Li and LI Kai.Synthesis and Crystal Structure of a Two-Fold Three-Dimesional Inorganic-Organic Hybrid Complex [Cd(C5H3N2O2)2(H2O)]n[J].Chinese Journal of Inorganic Chemistry,2009,25(3):560-562. | |
| Authors: | ZHANG Peng WANG En-Bo XING Chang-Yu KANG Ping-Li and LI Kai |
| Institution: | College of Chemistry, Liaoning University, Shenyang 110036; Faculty of Chemistry, Northeast Normal University, Changchun 130024,Faculty of Chemistry, Northeast Normal University, Changchun 130024,College of Chemistry, Liaoning University, Shenyang 110036,College of Chemistry, Liaoning University, Shenyang 110036 and College of Chemistry, Liaoning University, Shenyang 110036 |
| Abstract: | A three-dimensional two-fold inorganic-organic hybrid complex: Cd(C5H3N2O2)2(H2O)]n(1), was synthesized under mild hydrothermal condition, and the X-ray crystal structure analysis was used to determined the structure. The complex crystallizes in the orthorhombic space group Pbca, with a=1.147 6(2) nm, b=1.211 1(2) nm, c=1.750 3(4) nm, V=2.432 6(8) nm3, Z=8, R1=0.032 3, wR2=0.134 3. CCDC: 714446. |
| Keywords: | two-fold interpenetration three-dimensional hydrothermal synthesis crystal structure |
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