Synthesis of Iso-condensed Heteroaromatic Pyrroles and Their Application in the Preparation of Conducting Polymers |
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作者姓名: | Chin-Kang Sha V. Raghukumar |
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作者单位: | Department of Chemistry,National Tsing Hua University,Hsinchu 300,Department of Chemistry,National Tsing Hua University,Hsinchu 300 |
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摘 要: | Iso-condensed heteroaromatic pyrroles 1 are 10π-electron aromatic compounds. They are of interest from both theoretical and synthetic points of view. They are the cyclic analogues of heteroaromatic ortho-quinodimethanes 2, and can react with dienophiles in a Diels-Alder reaction to give the synthetically useful cycloadducts 3. Many of them are also of potential pharmaceutical importance because they are isosteric with indoles. Iso-condensed heteroaromatic pyrroles 1 can be used also as the m…
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