New ligand platforms for developing the chemistry of the Ti=N-NR2 functional group and the insertion of alkynes into the N-N bond of a Ti=N-NPh2 ligand |
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| Authors: | Selby Jonathan D Manley Catherine D Feliz Marta Schwarz Andrew D Clot Eric Mountford Philip |
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| Institution: | Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK OX1 3TA. |
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| Abstract: | Two broadly applicable strategies for extending the available ligand platforms of the virtually unexplored terminal Ti=N-NR2 functional group are described, along with the highly selective room temperature insertion of alkynes into the N-N bond of Ti{MeN(CH2CH2NSiMe3)2}(NNPh2)(py) and the catalytic cis-diamination of PhCtriple bond]CMe by diphenylhydrazine. |
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