| Condensation reaction of formaldehyde and methyl formate catalyzed by a composite catalyst system |
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| 引用本文： | Ke Bing Wang Gong Ying Wang. Condensation reaction of formaldehyde and methyl formate catalyzed by a composite catalyst system[J]. 中国化学快报, 2007, 18(7): 811-813. DOI: 10.1016/j.cclet.2007.05.004 |
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| 作者姓名： | Ke Bing Wang Gong Ying Wang |
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| 作者单位： | [1]Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China [2]Graduate School of Chinese Academy of Sciences, Beijing 100039, China |
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| 摘 要： | The condensation reaction of formaldehyde and methyl formate to form methyl glycolate and methyl methoxy acetate catalyzed by p-toluenesulfonic acid and different Lewis acid compounds has been investigated. The composite catalytic system consisting of p-toluenesulfonic acid and NiX2 （X = Cl, Br, I）, especially NiI2, exhibited a high catalytic performance for the condensation reaction, the total yield of MG and MMAc was up to 72.37%.
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| 关 键 词： | p-甲苯磺酸 甲醛 甲基甲酸化 甲基乙醇酸酯 甲氧基醋酸酯 |
| 修稿时间： | 2007-01-21 |
Condensation reaction of formaldehyde and methyl formate catalyzed by a composite catalyst system |
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| Ke Bing Wang,Gong Ying Wang. Condensation reaction of formaldehyde and methyl formate catalyzed by a composite catalyst system[J]. Chinese Chemical Letters, 2007, 18(7): 811-813. DOI: 10.1016/j.cclet.2007.05.004 |
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| Authors: | Ke Bing Wang Gong Ying Wang |
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| Affiliation: | 1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 61004l, China;2. Graduate School of Chinese Academy of Sciences, Beijing 100039, China |
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| Abstract: | The condensation reaction of formaldehyde and methyl formate to form methyl glycolate and methyl methoxy acetate catalyzed by p-toluenesulfonic acid and different Lewis acid compounds has been investigated. The composite catalytic system consisting of p-toluenesulfonic acid and NiX2 (X = Cl, Br, I), especially NiI2, exhibited a high catalytic performance for the condensation reaction, the total yield of MG and MMAc was up to 72.37%. |
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| Keywords: | p-Toluenesulfonic acid Formaldehyde Methyl formate Methyl glycolate Methyl methoxy acetate |
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