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Development and Characterization of Laccol Lacquer Blended with Urushiol Lacquer
Authors:Kenichiro Anzai  Bach Trong Phuc  Tetsuo Miyakoshi
Affiliation:1. Department of Applied Chemistry, School of Science and Technology , Meiji University , Kawasaki , Japan;2. Research Center for Polymer Materials , Hanoi University of Science and Technology , Hanoi , Vietnam
Abstract:A lacquer blending urushiol and laccol was investigated. The blended lacquer with 30wt.% urushiol and 100wt.% laccol has a good drying property and film hardness. 2-D-NMR and FD-MS measurements of the lacquer dimer showed that a transfer of radicals between urushiol and laccol occurred during the enzymatic polymerization, and 4-4′ biphenyl, 4-6′ (4′-6), and 6-6 (6-6′) dibenzofuran structures were obtained.
Keywords:Blended lacquer  Dimer  FD-MS  Laccol  NMR  Urushiol
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