Efficient Deallylation of Allyl Phenyl Ethers by Molecular Iodine in PEG-400 and Their Utility for Flavone Synthesis |
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| Authors: | Vivek Humne Pradeep Lokahnde |
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| Institution: | Center for Advance Studies, Department of Chemistry , University of Pune , Pune , India |
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| Abstract: | Rapid and efficient deallylation of allyl phenyl ethers by molecular iodine (20 mol%) in polyethylene glycol-400 at 60 °C has been reported. This method has short reaction time, readily available catalyst, and reuse of reaction medium with good yield. The utility of this methodology has been extended to flavone synthesis. Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.] |
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| Keywords: | Allyl phenyl ether deallylation flavones molecular iodine PEG-400 |
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