| 过氧化聚吡咯膜修饰微电极的制备及其电化学特性 |
| |
| 引用本文： | 万其进 张学记. 过氧化聚吡咯膜修饰微电极的制备及其电化学特性[J]. 分析化学, 1997, 25(9): 1031-1033 |
| |
| 作者姓名： | 万其进 张学记 |
| |
| 作者单位： | 湖北师范学院化学系!黄石435002(万其进)，武汉大学化学系!武汉430072(张学记，张春光，周性尧) |
| |
| 基金项目： | 国家自然科学基金，!省教委科研基金资助项目。 |
| |
| 摘 要： | 用电聚合法在铂微盘电极上制备了聚吡咯膜，并将其在电解质水溶液中进行了过氧化处理。所得到的过氧化膜是非电子导体而为离子导体，膜具有多孔笥的特征。该膜具有排有离子的作用，而对大阳离子如多巴胺具有高度的选择性。
|
| 关 键 词： | 微电极 过氧化 聚吡咯膜 化学修饰电极 多巴胺 |
Preparation of Overoxidized Polypyrrole Film Modified Microelectrode and Its Electrochemical Properties |
| |
| Wan Qijin.. Preparation of Overoxidized Polypyrrole Film Modified Microelectrode and Its Electrochemical Properties[J]. Chinese Journal of Analytical Chemistry, 1997, 25(9): 1031-1033 |
| |
| Authors: | Wan Qijin. |
| |
| Abstract: | Polypyrrole (PPy) film was electropolymerized on platinum disk microelectrode and treated by overoxidation in aqueous electrolyte solution. The film produced is electroni- cally non-conductive but ionically conductive and possesses porosity. This film has highly cation-selective properties such as for dopamine and can reject many interferences of aaions. The influencing factors of the film on the selective response of dopamine were also discussed.. |
| |
| Keywords: | Microelectrode overoxidized polypyrrole film chemically modified electrod dopamine |
| 本文献已被 CNKI 维普 等数据库收录！ |
