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SmI2-induced reductive cyclization of optically active β-alkoxyvinyl sulfoxides with aldehyde |
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| Authors: | Tomohiro Kimura Mayumi Hagiwara Tadashi Nakata |
| Institution: | aDepartment of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan |
| Abstract: | SmI2-induced reductive cyclization of optically active (E)- and (Z)-β-alkoxyvinyl sulfoxides with aldehyde was developed for the construction of several stereoisomers of tetrahydropyran derivatives. |
| Keywords: | Samarium diiodide C–C bond formation Polycyclic ethers Ethynyl p-tolylsulfoxide Tetrahydropyranol |
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