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| 闭式硼烷[B10H10]2－的反应性及其衍生物的应用研究进展 | |
| 引用本文： | 聂永,陈海艳,苗金玲,孙国新,窦建民.闭式硼烷[B10H10]2－的反应性及其衍生物的应用研究进展[J].有机化学,2009,29(6):822-834. |
| 作者姓名： | 聂永 陈海艳 苗金玲 孙国新 窦建民 |
| 作者单位： | 1. 济南大学化学化工学院,济南,250022 2. 聊城大学化学化工学院,聊城,252059 |
| 基金项目： | 济南大学博士启动基金，山东省重点学科基金 |
| 摘 要： | 多面体硼烷化合物以其独特的结构、成键和多方面的潜在应用价值而被广泛研究. 综述了近20年来闭式(closo)硼烷B10H10]2－的反应性(笼上氢取代、开笼-重排、开笼-金属插入等类型)及其衍生物的应用(硼中子俘获肿瘤治疗、放射性同位素萃取分离、新型材料、超分子化学等方面)研究进展. |
| 关 键 词： | 硼烷 簇合物 闭式- 反应性 |
| 收稿时间： | 2008-3-31 |
| 修稿时间： | 2008-7-26 |
Advances in the Chemistry and Applications of the Borane Anion Closo-[B10H10]2- and Its Derivatives |
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| Nie Yong,Chen Haiyan,Miao Jinling,Sun Guoxin,Dou Jianmin.Advances in the Chemistry and Applications of the Borane Anion Closo-[B10H10]2- and Its Derivatives[J].Chinese Journal of Organic Chemistry,2009,29(6):822-834. | |
| Authors: | Nie Yong Chen Haiyan Miao Jinling Sun Guoxin Dou Jianmin |
| Institution: | (a School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022) (b Department of Chemistry, Liaocheng University, Liaocheng 252059) |
| Abstract: | In the present paper, the reactivity (hydride substitution, cage opening-rearrangement and cage opening-metal insertion, etc.) of the widely studied closo-borane anion B10H10]2－ and potential applications (to boron neutron capture therapy of tumors, extraction of radioactive isotopes, new materials and su-pramolecular chemistry, etc.) of its derivatives are reviewed, covering the literature in the past 20 years. |
| Keywords: | borane cluster closo-[B10H10]2－ reactivi |
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