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Specific adsorption of azide ions on mercury electrodes from constant ionic strength solutions
Authors:Ernesto R González
Institution:Instituto de Física e Química de São Carlos, Universidade de São Paulo, C.P. 369, 13560 São Carlos-SP (Brasil)
Abstract:The adsorption of azide ions on mercury from aqueous solutions of NaN3+NaF at constant ionic strength has been studied by measurements of the double layer capacity. Taking into account changes in the structure of the diffuse layer, it was possible to show that the properties of the inner layer are similar to those observed previously in solutions of pure NaN3, and that the same adsorption isotherm applies to both systems.
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