On the temperature behaviour of an adsorption system described by a Frumkin-type isotherm |
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Authors: | Yu.Ya. Gurevich Yu.I. Kharkats |
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Affiliation: | Institute of Electrochemistry, Academy of Sciences of the U.S.S.R., Moscow V-71 (U.S.S.R.) |
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Abstract: | A theory is developed describing stepwise coverae changes with temperature in a system of adsorbed species interacting on the surface. The temperature patterns of coverage is shown to be significantly more interesting and variegated than the concentration pattern. The existence of double transitions in the system is predicted and the conditions for their realization are analyzed. |
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