The electrochemical behaviour and electron spin resonance spectroscopy of some heterocyclic organoboron compounds |
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| Authors: | M.F. El-Shazly |
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| Affiliation: | Chemistry Department, Faculty of Science, Science Center for Advancement of Post Graduate Studies, Alexandria University, Alexandria (Egypt) |
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| Abstract: | Some heterocyclic organoboron compounds derived from the reaction of 1,2-disubstituted benzene with m-nitrophenyl boronic acid have been investigated electrochemically. All the compounds exhibit two irreversible reduction waves. Controlled-potential electrolysis at the plateau of the second wave leads to decomposition and formation of nitrophenyl boronic acid radical anions. Electron spin resonance spectroscopy has been carried out to investigate the nature of these radical anions. |
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