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Anodic chlorination of aromatic compounds in acetic acid part II
Authors:Marina Mastragostino  Giuseppe Casalbore  Sergio Valcher  Luciana Pastorelli
Affiliation:1. Laboratorio di Polarografia ed Elettrochimica Preparativa del C.N.R., Corso Stati Uniti 10, 35100 Padova (Italy);2. Centro di Studio di Elettrochimica Teorica e Preparativa (Istituto Chimico G. Ciamician) Università di Bologna, via Selmi 2, 40126 Bologna (Italy)
Abstract:The anodic chlorination of aromatic compounds in anhydrous acetic acid has been further investigated. Evidence has been found for two different methods of electrochemical chlorination, in the systems Cl2/aromatic compounds and Cl?/aromatic compounds. These methods were also compared with the uncatalyzed chemical chlorination reaction. The yields of monochlorinated products and the related isometric distributions were taken into account. Since the isomeric distributions are equal with chemical and electrochemical chlorination methods, the formation of the same intermediate was proposed for both.
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