A near-infrared phosphor doped with Cr3+ towards zero-thermal-quenching for high-power LEDs |
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| Authors: | J. Li H. Zhe H. Ming Y. Zhou Y. Ye Q. Zhou Z. Wang |
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| Affiliation: | 1. Key Laboratory of Green-chemistry Materials in University of Yunnan Province, Key Laboratory of Advanced Synthetic Chemistry (Yunnan Minzu University) of State Ethnic Affairs Commission, School of Chemistry & Environment, Yunnan Minzu University, Kunming, 650500, PR China;2. State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, South China University of Technology, Guangzhou, 510641, PR China |
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| Abstract: | Cr3+-doped phosphors show significant application potential in near-infrared (NIR) light-emitting diodes (LEDs). However, the development of thermally stable and efficient NIR phosphors still faces enormous challenges. Herein, NIR phosphors K2NaMF6:Cr3+ (M3+ = Al3+, Ga3+, and In3+) were synthesized by the hydrothermal method. The represented K2NaAlF6:Cr3+ phosphor can be effectively excited by blue light (～430 nm) to present broadband emission at half a maximum of 96 nm peaking at ～ 728 nm. Meanwhile, the K2NaAlF6:Cr3+ phosphor exhibits excellent internal quantum efficiency (IQE = 68.08%) and nearly zero-thermal-quenching behavior, which is able to maintain 96.5% emission intensity at 150 °C of the initial value at 25 °C. The NIR phosphor-converted LED was fabricated based on K2NaAlF6:Cr3+ phosphor and a blue LED chip, showing a NIR output power of 394.39 mW at 300 mA with a high photoelectric conversion efficiency of 10.9% at 20 mA. Using the high-power NIR LED as a lighting source, transparent and quick veins imaging as well as non-destructive testing were demonstrated, suggesting the NIR phosphor has a wide range of practical applications. |
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| Keywords: | Fluorides High thermal stability Non-destructive testing Veins imaging NIR LEDs |
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