Surface treatment of lignocellulose biofiller for fabrication of sustainable polylactic acid biocomposite with high crystallinity and improved burning antidripping performance |
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Authors: | Z.C. Lule J. Kim |
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Affiliation: | 1. School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul, 06974, Republic of Korea;2. Department of Advanced Materials Engineering, Chung-Ang University, Anseong-Si, Gyeonggi-do, 17546, Republic of Korea |
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Abstract: | In this work, we incorporated surface-treated coffee husks (CHs) into a polylactic acid matrix to fabricate environmentally friendly composites, with high crystallinity and satisfactory antidripping performance for flame retardancy. CHs are lignocelluloses that contain cellulose, hemicellulose, and lignin that are present as interlinked complex macromolecular structure. CH spectroscopic characterization confirmed that the phytic acid/amine silane agent was successfully attached and bonded with the cellulose portion of CHs. Morphological analysis of the composites revealed that the surface-treated CHs helped to improve the interfacial interaction between the filler and the matrix. Furthermore, the differential scanning calorimetry analysis showed that the crystallinity of the composites increased with CH loading. Flammability and combustion tests confirmed that the combined effect of P/Si/N on surface treatment improved the flame retardance behavior of the composites. The tensile strength and modulus of the composites exhibited a 28.7% and 34.4% increase compared with the corresponding composite with raw CHs. |
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Keywords: | Coffee husk Composite Mechanical properties Flame retardancy |
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