Über Erdalkalimetalloxogallate. VIII Synthese und Aufbau eines neuen Calciumoxogallats: Ca3Ga4O9 |
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Authors: | Axel-Rüdiger Schulze Hanskarl Müller-Buschbaum |
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Affiliation: | (1) Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, D-2300 Kiel, Bundesrepublik Deutschland |
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Abstract: | The hitherto unknown compound Ca3Ga4O9 was prepared and investigated by X-ray single crystal methods. Ca3Ga4O9 has orthorhombic symmetry:a=1435.8;b=1682.5;c=532.1 pm; space group C2v11–Cmm2,Z=6. The tetrahedra network (circles of 4 and 5 GaO4-tetrahedra) and the surrounding of Ca2+ are described and discussed with respect to other oxogallates. |
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Keywords: | Calcium Gallium Oxygen Single Crystal X-Ray |
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