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Über Erdalkalimetalloxogallate. VIII Synthese und Aufbau eines neuen Calciumoxogallats: Ca3Ga4O9
Authors:Axel-Rüdiger Schulze  Hanskarl Müller-Buschbaum
Affiliation:(1) Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, D-2300 Kiel, Bundesrepublik Deutschland
Abstract:The hitherto unknown compound Ca3Ga4O9 was prepared and investigated by X-ray single crystal methods. Ca3Ga4O9 has orthorhombic symmetry:a=1435.8;b=1682.5;c=532.1 pm; space group C2v11–Cmm2,Z=6. The tetrahedra network (circles of 4 and 5 GaO4-tetrahedra) and the surrounding of Ca2+ are described and discussed with respect to other oxogallates.
Keywords:Calcium  Gallium  Oxygen  Single Crystal  X-Ray
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