Rhodium carbonyl cluster chemistry. Synthesis and chemical characterization of the anion [Rh6(CO)14]4− |
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| Authors: | Secondo Martinengo Alessandro Fumagalli Paolo Chini |
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| Institution: | Centro C.N.R. di Studio sulla Sintesi e la Struttura dei Composti dei Metalli di Transizione nei Bassi Stati di Ossidazione and Istituto di Chimica Generale dell''Universita'', Via G. Venezian 21, 20133 Milano Italy |
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| Abstract: | The anion Rh6(CO)14]4? has been isolated from the reaction of Rh6(CO)16] with alkali hydroxides in aqueous solution. It shows high reactivity towards electrophiles and in redox condensations with other rhodium clusters; and is rapidly decomposed by carbon monoxide. |
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