A facile synthesis of complexes of the type Ru(η5-C5H5)L2H (L2 = chelating phosphine) |
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| Authors: | Colin White Edoardo Cesarotti |
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| Institution: | Department of Chemistry, University of Sheffield, Sheffield S3 7HF Great Britain;Dipartimento di Chimica Inorganica e Metallorganica, Centro CNR, Via Venezian 21, 20133 Milano Italy |
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| Abstract: | Ru(C5H5)(CO)2H, prepared in situ from Ru3CO)12, reacts with bisphosphines L2 to give Ru(C5H5)L2H quantitatively L2 = Ph2P(CH2)nPPh2n = 2 or 4; L2 = (R)-Ph2PCH2CH(Me)PPh2]. |
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