Synthesis of hetero-binuclear derivatives of the tetrathiolato complexes [Mo(η-C5H5CH2SR)2)], R = Prn and Ph,with platinum,palladium, and rhodium |
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| Authors: | Dermot O&#x;hare Malcolm LH Green FGeoffrey N Cloke |
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| Institution: | Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR Great Britain |
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| Abstract: | The compound Mo(η-C5H4(CH2)2SPrn)2(SPrn)2 acts as a bidentate ligand giving the heteronuclear bi-metallic compounds Mo(η-C5H4CH2CH2SPrn)2-(SPrn)2(PtCl2)],Mo(η-C5H4CH2CH2SPrn)2(SPrn)2(PdCl2)2], Mo(η-C5C4CH2CH2SPrn)2(SPrn)2(RhCl3)2], Mo(η-C5H4CH2CH2SPrn)2(μ-SPrn)2Rh(dppe)]BF4, Mo(η-C5H4CH2CH2SPrn)2(μ-SPrn)2(COD)Rh]Cl, Mo(η-C5H4CH2CH2SPrn)2-(μ-SPrn)2Pt(PPh3)2](PF6)2, and the compound Mo(η-C5H4(CH2)2-μ-SPh)2Cl2Rh(COD)]Cl bonds via the ring-sulphur substituents giving Mo(η-C5H4(CH2)2-μ-SPh)2-Cl2Rh(COD)]Cl. |
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