Isolation of cis- and trans-[SnR2] configurational isomers of the octahedral complex,dichlorobis(4-chlorophenyl)tin(IV)-4,4′-dimethyl-2,2′-bipyridyl |
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| Authors: | VGKumar Das Yap Chee Keong Peter J Smith |
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| Institution: | Chemistry Department, University of Malaya, Kuala Lumpur 22-11 Malaysia;International Tin Research Institute, Greenford, Middlesex UB6 7AQ Great Britain |
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| Abstract: | The coordinative interaction between dichlorobis(4-chlorophenyl)tin(IV) and the chelating ligand, 4,4′-dimethyl-2-2′-bipyridyl (dmbipy), has allowed the isolation of both cis- and trans-SnR2] configurational isomers of the derived complex, Sn(4-ClC6H4)2Cl2(dmbipy)], constituting the first such case reported for octahedral SnR2X2L2] systems. |
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