Formation of 1,3-dienetricarbonyliron complexes from the reaction of dipotassium tetracarbonylferrate with allylic compounds |
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Authors: | Yasuo Butsugan Akihiko Yamashita Shuki Araki |
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Institution: | Department of Synthetic Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466 Japan |
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Abstract: | The reaction of dipotassium tetracarbonylferrate with various allylic phosphates and halides gives 1,3-dienetricarbonyliron complexes. The formation of the complexes is highly stereoselective depending on the geometry of the allylic compounds used. |
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