Struktur und reaktivität des koordinativ überladenen komplexes dichloro-η5 -cyclopentadienyl- tris(tetrahydrofuran)ytterbium(III) |
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| Authors: | Martin Adam Xing-fu Li Wolfgang Oroschin R Dieter Fischer |
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| Institution: | Institut für Anorganische and Angewandte Chemie der UniversitätHamburg, Martin-Luther-King-Platz 6, D-2000 Hamburg 13, F.R.G. |
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| Abstract: | The crystal and molecular structure of (η5 -C5H5)YbCl2(THF)3 (1), which crystallizes e.g. from solutions of (C5H5)2YbCl]2 in THF, fully corresponds to the structure of the previously examined Er-homologue. In accordance with its rather high SAS-value (0.784), 1 loses spontaneously two THF ligands when exposed to toluene. |
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