|
|||||
|
|
Syntheses of metal carbonyls: XVII. Formation of a heteronuclear organometallic cluster containing ruthenium and rhodium; crystal and molecular structure of {[Rh(η-C5Me5)]3Ru(CO)3](μ3-CO)2} |
|
| Authors: | Russell P. Hughes Arnold L. Rheingold Wolfgang A. Herrmann John L. Hubbard |
| Affiliation: | Departments of Chemistry, Dartmouth College, Hanover, New Hampshire 03755 U.S.A.;University of Delaware, Newark, Delaware 19711 U.S.A.;Institut fur Anorganische Chemie der Universität, Niederurseler Hang, D -6000 Frankfurt am Main 50 Federal Republic of Germany |
| Abstract: | Ru(C6Me6)(C2H4)2 reacts with Rh(C5Me5)(CO)2 to give the known dinuclear complex [Rh(C5Me5)(CO)]2 and the new heteronuclear cluster complex {[Rh(C5Me5)]3[Ru(CO)3](μ3-CO)2} which has been fully characterized by a single crystal X-ray diffraction study. |
| Keywords: | Dartmouth College. Author to whom correspondence should be addressed Alfred P. Sloan Research Fellow 1980–1984. Alexander von Humboldt Research Fellow University of Frankfurt 1983–1984. |
| 本文献已被 ScienceDirect 等数据库收录！ | |