Duroquinonerhodium(I) complexes. Crystal structure of [Rh(DQ)(C6H5Me)]PF6 |
| |
| Authors: | M. Valderrama M. Scotti R. Ganz L.A. Oro F.J. Lahoz C. Foces-Foces F.H. Cano |
| |
| Affiliation: | Facultad de Química, Pontificia Universidad Católica de Chile Casilla 6177, Santiago Chile;Departamento de Química Inorgánica, Universidad de Zaragoza, 50009 Zaragoza Spain;Departamento de Rayox-X, Instituto Rocasolano, CSIC, Serrano 119, Madrid Spain |
| |
| Abstract: | The preparation of cationic arenerhodiiim(I) complexes of the type [Rh(DQ)-(arene)]PF6 (DQ = duroquinone; arene = C6H6-nMen, n duroquinone complexes with Group VB donor ligands are described. The crystal structure of [Rh(DQ)(C6H5Me)]PF6 has been determined by X-ray diffraction. The compound crystallizes in the P21/n space group, in a unit cell of dimensions a 15.9866(5), b 11.8438(3), c 9.9968(3) Å, β 98.473(4)Å. The structure was solved by Patterson and Fourier methods and refined to R and Rw values of 0.062 and 0.076, respectively. The Rh atom is coordinated to a toluene group (η6) and a duroquinone ligand (η4), which eclipse each other. Both ligands are distorted to adopt boat-like conformations. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
