The reactions of [Fe(CO)5-n(CNAr)n] (n = 1 or 2; Ar = aryl) with dicyclopentadiene |
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| Authors: | AR Manning Gerrard McNally Paul Soye |
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| Institution: | Department of Chemistry, University College, Belfield, Dublin 4 Ireland |
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| Abstract: | Although Fe(CO)3(CNAr)2] complexes fail to react with dicyclopentadiene at 140°C, under the same conditions Fe(CO)4(CNAr)] complexes give high yields of Fe2(η-C5H5(CO)3(CNAr)] and Fe2(η-C5H5)2(CO)2-(CNAr)2], with the product ratios depending very much on the aryl group (Ar). |
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