Radikalkomplexe vom typ Cp(CO)2MnXR. (X = S,Se) |
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| Authors: | Andreas Winter Gottfried Huttner Ibrahim Jibril |
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| Institution: | Lehrstuhl für Synthetische Anorganische Chemie, Universität Konstanz, Postfach 5560, D-7750 Konstanz B.R.D. |
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| Abstract: | CpMn(CO)2ER (E = S, Se) compounds 1] belong to the rare radical derivatives of the CpMn(CO)2 fragment. We describe herein the syntheses, electrochemistry, and organometallic reactions of Cp★Mn(CO)2SR 1 (1a: R = t-C4H9, 1b: R = 2-adamantyl) and CpM(CO)2SePh (2). |
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