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Radical addition of secondary phosphine chalcogenides to allylamine: Atom-economic synthesis of aminopropylphosphine chalcogenides |
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| Authors: | N K Gusarova S I Verkhoturova T I Kazantseva S N Arbuzova A I Albanov A A Tatarinova B A Trofimov |
| Institution: | 1. A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia |
| Abstract: | Secondary phosphine sulfides and phosphine selenides react with allylamine under the conditions of radical initiation (UV or AIBN) to form the anti-Markovnikov adducts in up to 93 % yield. |
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