Effect of plasticizer dibutyl phthalate on the thermal decomposition of nitrocellulose |
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Authors: | Ruichao Wei Shenshi Huang Zhi Wang Chengming Wang Tiannian Zhou Junjiang He Richard Yuen Jian Wang |
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Affiliation: | 1.State Key Laboratory of Fire Science,University of Science and Technology of China,Hefei,People’s Republic of China;2.Department of Civil and Architectural Engineering,City University of Hong Kong,Hong Kong,People’s Republic of China;3.Hefei National Laboratory for Physical Sciences at the Microscale,University of Science and Technology of China,Hefei,People’s Republic of China |
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Abstract: | This paper aims to investigate the effects of plasticizer dibutyl phthalate (DBP) on the thermal decomposition of nitrocellulose (NC) by using a series of analytical apparatuses. In the present study, the detailed structures of pure NC (NC-P) and NC with DBP (NC-D) were revealed by scanning electron microscope. It was found that the fibers in NC-D are more closely aligned than those in NC-P, which makes the thermal behaviors of NC-D different from NC-P. The thermal stability of both NC-P and NC-D was examined by means of simultaneous TG-DSC apparatus (STA). Three different kinetic methods (Kissinger–Akahira–Sunose method, Ozawa–Flynn–Wall method, and Friedman method) were applied for determining the activation energy E of these two NC samples. Moreover, the experimental data were compared with sigmoidal models and pre-exponential factor was calculated by compensation effect. Besides, in situ Fourier transform infrared (FTIR) and a TGA instrument coupled with Frontier FTIR spectrometer were employed to investigate the characteristic functional groups of decomposition residues and gaseous products at different temperatures, respectively. The results show that NC-P and NC-D have similar decomposition products and decomposition mechanisms. |
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