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Isotopic hydrogen exchange in σ-bonded ligand of σ-C6H5CH2MO(CO)3C5H5-π and σ-C6H5CH2W(CO)3C5H5-π complexes
Authors:T. Yu. Orlova  S. S. Churanov  L. A. Fedorov  V. N. Setkina  D. N. Kursanov
Affiliation:(1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR
Abstract:Conclusions Quantitative data were obtained as the result of studying the kinetics of isotopic hydrogen exchange in aci medium in thesgr-C6H5CH2Mo(CO)3C5H5-pgr andsgr-C6H5CH2W(CO)3C5H5-pgr complexes, which characterize the CH2M(CO)3C5H5-pgr substituents as being powerful electron donors.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1652–1654, July, 1973.
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