Isotopic hydrogen exchange in σ-bonded ligand of σ-C6H5CH2MO(CO)3C5H5-π and σ-C6H5CH2W(CO)3C5H5-π complexes |
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Authors: | T. Yu. Orlova S. S. Churanov L. A. Fedorov V. N. Setkina D. N. Kursanov |
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Affiliation: | (1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions Quantitative data were obtained as the result of studying the kinetics of isotopic hydrogen exchange in aci medium in the-C6H5CH2Mo(CO)3C5H5- and-C6H5CH2W(CO)3C5H5- complexes, which characterize the CH2M(CO)3C5H5- substituents as being powerful electron donors.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1652–1654, July, 1973. |
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