Matrix and convolution methods in chemical kinetics |
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Authors: | Lionello Pogliani Mário N. Berberan-Santos José M. G. Martinho |
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Affiliation: | (1) Dipartimento di Chimica, Università della Calabria, 87030 Rende (CS), Italy;(2) Centro de Quimica-Fisica Molecular, Instituto Superior Técnico, 1096 Lisboa Codex, Portugal |
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Abstract: | Two new approaches for writing kinetic equations in the matrix form or directly in the integrated form are presented here. While the first method allows to derive the kinetic rate matrix of kinetic systems of any kind in a direct and straightforward way, the second approach applies to species that are consumed solely through first order steps, regardless of the complexity of their formation pathways. |
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