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Supramolecular ferroelectric liquid crystals. Hydrogen-bonded complexes between benzoic acids and chiral stilbazoles
Authors:Hideyuki Kihara   Takashi Kato  Toshiyuki Uryu  Seiji Ujiie  Uday Kumar  Jean M. J. Fr  chet  Duncan W. Bruce  Daniel J. Price
Affiliation: a Institute of Industrial Science, The University of Tokyo, Tokyo, Japanb Department of Material Science, Shimane University, Matsue, Japanc Department of Chemistry, Baker Laboratory, Cornell University, Ithaca, New York, U.S.A.d Department of Chemistry, University of Exeter, Exeter, Englande Centre for Molecular Materials, University of Sheffield, England
Abstract:Supramolecular ferroelectric liquid crystalline complexes have been obtained from 4-alkoxybenzoic acids and optically active trans-4-substituted-4'-stilbazoles. Chiral smectic C phases are induced by the formation of supramolecular mesogenic structure through the selective intermolecular hydrogen bond between the achiral benzoic acids and the chiral non-mesogenic stilbazoles.
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