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RuCl3-TBHP mediated allylic oxidation of Δ lanosterol derivatives
Authors:Bapurao B Shingate  Braja G Hazra  Deepak B SalunkeVandana S Pore
Institution:Division of Organic Chemistry, National Chemical Laboratory, Pune 411 008, India
Abstract:A variety of Δ8(9)-lanosterol derivatives were converted into 7,11-dienones using t-butyl hydroperoxide in the presence of ruthenium chloride (RuCl3) in good yields.
Keywords:Allylic oxidation  Oxygenated steroids  Steroidal ketones  Ruthenium chloride  t-Butyl hydroperoxide
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