Pd(II)-catalyzed intermolecular 1,2-diamination of conjugated dienes |
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Authors: | Bar Grégory L J Lloyd-Jones Guy C Booker-Milburn Kevin I |
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Affiliation: | School of Chemistry, University of Bristol, Cantock's Close, UK. |
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Abstract: | A Pd(II) chloride precatalyst, in the presence of 1 equiv of benzoquinone, effects highly efficient, regioselective 1,2-diamination of 1,3-dienes using dialkyl ureas under mild conditions. There is no requirement for a large excess of diene. |
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