| 电沉积n—CdSe在多硫溶液界面上的电荷转移机理 |
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| 引用本文： | 唐瑞平. 电沉积n—CdSe在多硫溶液界面上的电荷转移机理[J]. 高等学校化学学报, 1991, 12(4): 532-536 |
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| 作者姓名： | 唐瑞平 |
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| 作者单位： | 上海交通大学应用化学系 200030(唐瑞平)，上海交通大学应用化学系 200030(孙壁媃) |
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| 摘 要： | 通过测定平带电位,澄清了OH~-离子在CdSe电极上的吸附情况,发现在S、S~(2-)、OH~-溶液中S~(2-)离子优先吸附,结合旋转环盘电极测量,证明n-CdSe电极在多硫溶液界面上的电荷转移过程。
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| 关 键 词： | 电沉积 多硫溶液 界面 电荷转移 |
The Charge Transfer Mechanism at the Interface of the Electrodeposited n-CdSe/Polysulfide Solutions |
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| Tang Rui-ping,Sun Bi-rou. The Charge Transfer Mechanism at the Interface of the Electrodeposited n-CdSe/Polysulfide Solutions[J]. Chemical Research In Chinese Universities, 1991, 12(4): 532-536 |
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| Authors: | Tang Rui-ping Sun Bi-rou |
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| Abstract: | From the determination of the flat-band potentials of the n-CdSe anodes in various polysul-fide solutions, the adsorption of OH- ions on the anodes under different conditions and the preferential adsorption of sulfide ions in S~, S2-, OH- electrolytic solutions are clarified. The charge transfer mechanism at the interface of n-CdSe in the pojysulfide solution is elucidated with the help of rotating ring-disk electrode measurements. |
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| Keywords: | Photoelectrochemistry Charge transfer n-CdSe/polysulfide solution interface |
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