A key to progress: Identification of the state of catalysts during the catalytic reaction |
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Authors: | B Delmon S Zeyss E Gaigneauz P Ruiz |
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Institution: | (1) Unité de catalyse et chimie des matériaux divisés, Université catholique de Louvain, Place Croix du Sud. 2/17, B-1348 Louvain-la-Neuve, (Belgium);(2) Fonds National de la Recherche Scientifique, (Belgium) |
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Abstract: | We stress the importance of identifying the state in which catalysts are during the catalytic reaction. Catalysts as prepared
do not correspond to the real working catalyst. Several examples will be recalled, and a new one (Mo-Te-O catalyst) will be
mentioned. In a more detailed way, it will be shown that the working state of MoO3 is MoxO3x-2 with 8 ≤x≤18. The pitfalls encountered when focusing on catalysts as prepared (as opposed to catalysts “as they work”) is
illustrated in the case of mixed SbxMoyOz oxides which decompose spontaneously during the reaction. |
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