| A CLUSTER COMPOUND WITH DI-ENDOXYGEN LIGANDS——THE CRYSTAL AND MOLECULAR STRUCTURE OF [Fe(MOS_4O)_2][N(C_2H_5)_4]3 |
| |
| 引用本文： | 王凤山,樊玉国,吕品喆,徐吉庆,刘喜生.A CLUSTER COMPOUND WITH DI-ENDOXYGEN LIGANDS——THE CRYSTAL AND MOLECULAR STRUCTURE OF [Fe(MOS_4O)_2][N(C_2H_5)_4]3[J].中国科学B辑(英文版),1986(6). |
| |
| 作者姓名： | 王凤山 樊玉国 吕品喆 徐吉庆 刘喜生 |
| |
| 作者单位： | Institute of Theoretical Chemistry，Jilin University，Changchun，Institute of Theoretical Chemistry，Jilin University，Changchun，Institute of Theoretical Chemistry，Jilin University，Changchun，Department of Chemistry，Jilin University，Changohun，Department of Chemistry，Jilin University，Changohun |
| |
| 摘 要： | Fe(MoS_4O)_2] N(C_2H_3)_4]_3 cluster compound with di-end-oxygen ligands has been prepared and characterized by the X-ray diffraction method. The compound crystallizes in a monoclinic space group P2_1/n with lattice parameters a=13.019(4), b=16.959(5), c=18.234(5), β=97.34(2)(°), Z=4. The final agreement factors are R=0.0740, Rw=0.0598. The terminal bond length, Mo-S_t and bridged one, MO-S_b for the compound are much longer than the counterpart without end-oxygen ligand. It possibly suggests that low valence of molybdenum and smaller electronegativity of sulphur than oxygen lead to the charge transfer as S→Mo→O.
|
| 本文献已被 CNKI 等数据库收录！ |
|
