Deoxygenative reduction of carbon dioxide to methane, toluene, and diphenylmethane with [Et2Al]+ as catalyst |
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| Authors: | Khandelwal Manish Wehmschulte Rudolf J |
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| Affiliation: | Department of Chemistry, Florida Institute of Technology, 150 West University Boulevard, Melbourne, FL 32901, USA. |
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| Abstract: | The strong Lewis acid [Et(2)Al](+) catalyzes the reduction of carbon dioxide with hydrosilanes under mild conditions to methane. In benzene solution, the side products toluene and diphenylmethane are also obtained through Lewis acid catalyzed benzene alkylation by reaction intermediates. |
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| Keywords: | CO2 reduction diethylaluminum homogeneous catalysis hydrosilanes Lewis acids |
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