Cyclometallated gold(III) hydroxides as versatile synthons for Au-N, Au-C complexes and luminescent compounds |
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| Authors: | Roşca Dragoş-Adrian Smith Dan A Bochmann Manfred |
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| Institution: | Wolfson Materials and Catalysis Centre, School of Chemistry, University of East Anglia, Norwich, NR4 7TJ, UK. |
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| Abstract: | The gold(III) hydroxide κ(3)-(C^N^C)*Au(OH) reacts with C-H and N-H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence from yellow to blue (C^N^C)* = 2,6-(C(6)H(3)Bu(t))(2)pyridine]. |
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