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Electrochemical mapping reveals direct correlation between heterogeneous electron-transfer kinetics and local density of states in diamond electrodes |
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| Authors: | Patten Hollie V Meadows Katherine E Hutton Laura A Iacobini James G Battistel Dario McKelvey Kim Colburn Alexander W Newton Mark E Macpherson Julie V Unwin Patrick R |
| Affiliation: | Department of Chemistry, University of Warwick, Coventry, UK. |
| Abstract: | Conducting carbon materials: a multi-microscopy approach shows that local heterogeneous electron-transfer rates at conducting diamond electrodes correlate with the local density of electronic states. This model of electroactivity is of considerable value for the rational design of conducting diamond electrochemical technologies, and also provides key general insights on electrode structure controls in electrochemical kinetics. |
| Keywords: | carbon electrochemistry electron transfer kinetics scanning electrochemical microscopy |
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