ZnMn3O7: A New Layered Cathode Material for Fast-Charging Zinc-Ion Batteries |
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作者姓名: | Ruitao Sun Qin Liu Wenzhuo Deng |
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作者单位: | 1. CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;2. University of Chinese Academy of Sciences |
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基金项目: | supported by the Fujian Science and Technology Key Project (No. 2021H0042); |
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摘 要: | Low-cost and high-energy-density manganese-based compounds are promising cathode materials for rechargeable aqueous zinc-ion batteries(AZIBs), however, they often experience cycling instability issues and inferior rate capability. Herein, we report a new layered manganese-based cathode material, ZnMn3O7(ZMO), which possesses a large interlayer spacing of 4.8 ? and allows the intercalation of ~1.23 Zn-ions per formula unit(corresponding to a capacity of ~170 m Ah/g). Importa...
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