Glycosulfoxides in carbohydrate chemistry |
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| Authors: | Maria Chiara Aversa [Author Vitae]Author Vitae] Paola Bonaccorsi [Author Vitae] |
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| Affiliation: | Dipartimento di Chimica organica e biologica, Università degli Studi di Messina, Salita Sperone 31 (vill. S. Agata), 98166 Messina, Italy |
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| Abstract: | |
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| Keywords: | Ac, acetyl AIBN, (E)-2,2&prime -azobis(2-methylpropionitrile), NCCMe2N=NCMe2CN All, allyl aq, aqueous Bn, benzyl BSNPO, 2-benzenesulfonyl-3-(m-nitrophenyl)oxaziridine Bu, butyl Bz, benzoyl CD, cyclodextrin Cy, cyclohexyl DCM, dichloromethane DFT, density functional theory DMAP, 4-dimethylaminopyridine DMF, N,N-dimethylformamide DTBMP, 2,6-di-tert-butyl-4-methylpyridine equiv, equivalent(s) Et, ethyl h, hour(s) HFIP, 1,1,1,3,3,3-hexafluoro-2-propanol HIV, human immunodeficiency virus i, iso LAH, lithium aluminium hydride LB, Langmuir-Blodgett LDA, lithium diisopropylamide Lev, levulinoyl (3-acetylpropanoyl) lp, lone pair m, meta m-CPBA, m-chloroperbenzoic acid Me, methyl min, minutes MMPP, magnesium monoperoxyphthalate mol, molar or moles MOM, methoxymethyl MPAA, (S)-α-methoxyphenylacetic acid MPM, 4-methoxyphenylmethyl NBS, N-bromosuccinimide NIS, N-iodosuccinimide NMNO, N-methylmorpholine N-oxide NMR, nuclear magnetic resonance NPhth, N-phthalimido NTCP, N-tetrachlorophthalimido Nu, nucleophile o, ortho oxone, potassium peroxymonosulfate (2KHSO5· KHSO4· K2SO4) p, para P, protecting group Ph, phenyl Piv, pivaloyl (2,2-dimethylpropanoyl) PMB, p-methoxybenzyl PMP, p-methoxyphenyl Py, pyridine Ra, Raney rt, room temperature Selectfluor, 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane (N-chloromethyl-N&prime -fluorotriethylenediammonium) bis(tetrafluoroborate), F-TEDA-2BF4 SGLT2, sodium-dependent glucose transporter 2 t, tertiary (tert) TBDMS (TBS), tert-butyldimethylsilyl TBDPS, tert-butyldiphenylsilyl Tebbe reagent, bis(cyclopentadienyl)-μ-chloro(dimethylaluminum)-μ-methylenetitanium TEMPO, 2,2,6,6-tetramethylpiperidyl-1-oxy radical Tf2O, trifluoromethanesulfonic (triflic) anhydride TFA, trifluoroacetic acid TFAA, trifluoroacetic anhydride TfOH, trifluoromethanesulfonic (triflic) acid THF, tetrahydrofuran THP, tetrahydro-2H-pyran-2-yl TMS, trimethylsilyl TMSOTf, trimethylsilyl trifluoromethanesulfonate Tol, p-tolyl Triton B, benzyltrimethylammonium hydroxide Troc, 2,2,2-trichloroethoxycarbonyl Ts, tosyl (p-toluenesulfonyl) TTBP, 2,4,6-tri-tert-butylpyrimidine |
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