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| 氮掺杂的三层碳纳米管的制备 | |
| 引用本文： | 王志永,赵可可,施祖进,顾镇南,金朝霞.氮掺杂的三层碳纳米管的制备[J].无机化学学报,2008,24(8):1237-1241. |
| 作者姓名： | 王志永 赵可可 施祖进 顾镇南 金朝霞 |
| 作者单位： | 1. 北京分子科学国家实验室,稀土材料化学及应用国家重点实验室,北京大学化学与分子工程学院,北京,100871 2. 北京分子科学国家实验室,稀土材料化学及应用国家重点实验室,北京大学化学与分子工程学院,北京,100871;中国人民大学化学系,北京,100872 3. 中国人民大学化学系,北京,100872 |
| 基金项目： | 国家自然科学基金 , 科技部973MOST , 863 |
| 摘 要： | 利用气相扩散法将酞菁铁分子填充入双层碳纳米管的内部空腔中，通过高温加热使酞菁铁裂解，制备了氮掺杂的三层碳纳米管。高分辨透射电子显微镜观测表明，由酞菁铁生成的内层管的缺陷较多，管壁不平直，并且有竹节状结构，这可能是由于氮原子引起的。在电子束照射下，内层管的稳定性较差。通过与酞菁铁在宏观基底上的裂解作比较，探讨了三层碳纳米管的生成机理。 |
| 关 键 词： | 双层碳纳米管 三层碳纳米管 酞菁铁 氮 限域 |
Preparation of Nitrogen-Doped Triple-Walled Carbon Nanotubes |
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| WANG Zhi-Yong,ZHAO Ke-Ke,SHI Zu-Jin,GU Zhen-Nan and JIN Zhao-Xia.Preparation of Nitrogen-Doped Triple-Walled Carbon Nanotubes[J].Chinese Journal of Inorganic Chemistry,2008,24(8):1237-1241. | |
| Authors: | WANG Zhi-Yong ZHAO Ke-Ke SHI Zu-Jin GU Zhen-Nan and JIN Zhao-Xia |
| Institution: | Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications,College of Chemistry and Molecular Engineering, Peking University, Beijing 100871,Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications,College of Chemistry and Molecular Engineering, Peking University, Beijing 100871; Department of Chemistry, Renmin University of China, Be,Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications,College of Chemistry and Molecular Engineering, Peking University, Beijing 100871,Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications,College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 and Department of Chemistry, Renmin University of China, Beijing 100872 |
| Abstract: | |
| Keywords: | DWNTs TWNTs iron phthalocyanine nitrogen confinement |
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