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Extended Network via π…π Interaction and Hydrogen Bond Linkages of 1D Copper(II) Coordination Polymer: Synthesis, Crystal Structure and Characterization of [Cu(4,4′-bpy)(2-pzc)- (H_2O)]ClO_4·H_2O (2-pzc=2-pyrazine-5-carboxylate; 4,4′-bpy
引用本文:罗军华,陈丽华,洪茂椿,王瑞虎,曹荣,韩磊,翁家宝,林郑忠.Extended Network via π…π Interaction and Hydrogen Bond Linkages of 1D Copper(II) Coordination Polymer: Synthesis, Crystal Structure and Characterization of [Cu(4,4′-bpy)(2-pzc)- (H_2O)]ClO_4·H_2O (2-pzc=2-pyrazine-5-carboxylate; 4,4′-bpy[J].中国化学,2003(5).
作者姓名:罗军华  陈丽华  洪茂椿  王瑞虎  曹荣  韩磊  翁家宝  林郑忠
作者单位:State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China,Jian′ou Insitute of Environment Supervision,Fujian 353100,China,State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China,State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China,State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China,State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China,State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China,State Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China
基金项目:ProjectsupportedbytheNationalNaturalScienceFoundation (No .2 982 5 10 3 )ofChina,theNaturalScienceFoundation (No .8982 0 0 3 )ofFu jianProvinceandChineseAcademyofSciences .
摘    要:Introduction  Functionalcoordinationpolymersareofgreatinterestduetotheirpotentialapplicationsinmanyareas ,suchasmi croporosity ,electricalconductivity ,molecularmagnetism ,linearopticalbehaviororcatalysis .1 6 Considerableefforthasbeenfocusedonthesupramolecularnetworksassembledbycovalent,hydrogenbonds ,π…πinteractionorotherweakin teractionsowingtotheirfascinatingstructuraldiversityandpotentialapplicationindesignofporousmaterialswithnovelinclusionorreactivitypropertiesandsupramoleculardevi…

关 键 词:crystal  structure    4  4′  bipyridine    2  pyrazine  5  carboxylic    copper(II)  polymer    π…π  interaction  and  hydrogen  bonding
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