| 用原子矩阵法对工业级次氯酸钠水溶液宏观动力学研究 |
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| 引用本文： | 刘少友 黄雪莉. 用原子矩阵法对工业级次氯酸钠水溶液宏观动力学研究[J]. 新疆大学学报(理工版), 2004, 21(1): 109-112 |
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| 作者姓名： | 刘少友 黄雪莉 |
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| 作者单位： | 新疆大学化学化工学院，新疆乌鲁木齐830046 |
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| 摘 要： | 用原子矩阵法探讨了次氯酸钠水溶液的不稳定性及其影响因素。结果表明，NaClO的强氧化性主要是靠NaClO分解出的原子氧[O]而得以体现，反应时间越长，分解越彻底，次氯酸钠水溶液的反应宏观表现为准一级反应，浓度和温度都不同程度地影响了次氯酸钠水溶液的稳定性。
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| 关 键 词： | 原子矩阵法 反应动力学 次氯酸钠水溶液 强氧化剂 反应条件 原子衡算原理 反应级数 反应活化能 |
| 文章编号： | 1000-2839(2004)01-0109-04 |
| 修稿时间： | 2002-09-16 |
Study on the General Kinetics of Aqueous Sodium Hypochlorite Solution by Atomic Matrix Method |
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| LIU Shao-you,HUANG Xue-li. Study on the General Kinetics of Aqueous Sodium Hypochlorite Solution by Atomic Matrix Method[J]. Journal of Xinjiang University(Science & Engineering), 2004, 21(1): 109-112 |
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| Authors: | LIU Shao-you HUANG Xue-li |
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| Abstract: | In this paper,the unstability and its effect factors of aqueous sodium hypochlorite solutiion were studied by the method of atomic matrix.It was shown that strong oxidisability of sodium hypochorite primarily depends on atom-oxygen[O] releasing from the decomposition reaction of sodium hypochlorite,and that the longer time passed, the more sodium hypochlorite can be decomposited.The reaction of sodium hypochlorite can be described as a quasi-one -order reaction in general appearance.Both temperature and concentration affect the stability of sodium hypochlorite in different degree. |
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| Keywords: | atomic Matrix method aqueous sodium hypochlorite solution reaction kinetics |
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